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Kinetics and Microstructural Control

· If a large casting is formed, different parts cool at different rates and the overall microstructure tends to be course-grained.
· Slow cooling through the austenite range causes nucleation and growth to occur at high temperatures. This yields a few fast-growing nuclei that give large grains of austenite. These transform into a complex pearlite structure with ferrite on the grain boundaries (hypoeutectoid starting composition).
· Re-heating into the temperature range where austenite is stable, heterogeneously nucleates small austenite crystals. When the material is taken to room temperature in a controlled way these convert to a fine grained pearlite (Ferrite plus Fe3C).